摘要 四苯乙烯衍生物具有很多独特的光电性能和生物活性，在生物成像和光电材料等很多范围的应用前景都非常广泛。本文阐述了以二苯基酮为原料，首先合成四苯乙烯，然后由发烟硝酸和醋酸氧化，得到四硝基四苯乙烯，接着还原得到四氨基四苯乙烯，然后与三氯三嗪反应得到8-氯-四苯乙烯衍生物，产物再与乙胺反应，得到四乙基-四氯-四苯乙烯衍生物，最后再与烯丙基胺反应得到四烯丙基胺-四乙胺-四苯乙烯衍生物。最后经过质谱、元素分析、核磁氢谱和碳谱对该配合物进行全方面的表征，同时对在试验过程当中对有可能影响收率的影响因素（反应温度、反应时间、催化剂的类型等）进行实验研究，从而通过改变反应条件来提高产物的收率。

关键词： 四苯乙烯；四苯乙烯衍生物； 光电性能

Synthesis of four - allyl - four ethylamine-four styrene derivatives 

Abstract：etrastyrene derivatives have a lot of unique photoelectric properties and biological activities, and they have a wide range of application prospects in many fields such as bioimaging and photoelectric materials. This article describes the use of diphenyl ketone as raw material, the first synthesis of tetrastyrene, and then by the oxidation of fuming nitric acid and acetic acid, to obtain tetranitro tetrastyrene, followed by reduction to tetraaminotetrazole, and then reacted with trichlorotriazine An 8-chloro-tetrastyryl derivative is obtained, and the product is reacted with ethylamine to obtain a tetraethyl-tetrachloro-tetrastyrene derivative, and finally reacted with allylamine to obtain tetraallylamine-tetraethylamine. -tetrastyryl derivatives. Finally, the complexes were characterized by mass spectrometry, elemental analysis, nuclear magnetic protons and carbon spectra. At the same time, the influencing factors (reaction temperature, reaction time, type of catalyst, etc.) that may affect the yield during the test were analyzed. Experimental studies were conducted to improve the yield of the product by changing the reaction conditions.

Keywords ：four styrene, four styrene derivatives, characterization. Derivatives

目录

1绪论5

2文献综述.5

2.1本课题研究的目的和意义5

2.2 四苯乙烯的概述5

2.3 四苯乙烯衍生物的制备方法6

2.4 四苯乙烯的研究进展.7

2.4.1有关四苯乙烯AIE特性机制研究.7

2.4.3苯环上取代对四苯乙烯的聚集诱导发光特性的影响7

2.5 四苯乙烯在孔材料中的应用研究..8

2.5.1四苯乙烯在共价微孔聚合物的应用研究8

2.5.2 TPE在金属有机共价框架中（MOFs）的应用研究.8

2.5.3 基于四苯乙烯的荧光探针的应用9

2.5.4 四苯乙烯衍生物的其他应用.9

3 实验部分11

3.1试剂与仪器.11

3.1.1试剂列表11

3.1.2仪器列表..12

3.1.3试剂的物理常数13

3.2实验步骤13

3.2.1 四苯乙烯的合成步骤13

3.2.2 四硝基四苯乙烯的合成步骤.14

3.2.3 四氨基四苯乙烯的合成步骤14

3.2.4 8-氯-四苯乙烯衍生物的合成步骤15

3.2.5四乙基-四氯-四苯乙烯衍生物的合成步骤16

3.2.6四烯丙基胺-四乙胺-四苯乙烯衍生物的合成步骤16

4 结果分析及讨论17

4.1实验过程中的影响因素.17

4.1.1合成四苯乙烯实验过程中的影响因素17

4.1.2合成四硝基四苯乙烯实验过程中的影响因素17

4.1.3合成四氨基四苯乙烯实验过程中的影响因素18

4.1.4合成8-氯-四苯乙烯衍生物实验过程中的影响因素.19

4.1.5合成四乙基-四氯-四苯乙烯衍生物实验过程中的影响因19

4.1.6合成四烯丙基胺-四乙胺-四苯乙烯衍生物实验过程中的影响因素19 四烯丙基胺-四乙胺-四苯乙烯衍生物的合成:http://www.chuibin.com/huaxue/lunwen_205531.html